琥珀酸酐修饰的单氨基四苯基卟啉的合成与表征
DOI:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

河北省自然科学基金项目(B2008000709)的资助


Synthesis and characterization of mono amino tetraphenylporphyrin modified by succinic anhydride
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    卟啉化合物具有特殊的理化性质和生理功能,已经成为研究热点之一。在卟啉分子中引入亲水基团例如羧基可以提高其水溶性。本文利用琥珀酸酐对单氨基四苯基卟啉进行了修饰,将一个羧基引入卟啉分子。采用核磁共振、红外光谱、紫外可见光谱等手段对产物进行了表征,实验结果为首次报道。元素分析所得结果与理论计算值一致。同时,报道了产物4-氧代-4-((4-(10,15,20-三苯基-21H,23H-卟啉-5-基)苯基)氨基)丁酸的溶解性质。

    Abstract:

    Porphyrin and its derivatives is one of the research focuses because of its special physical and chemical properties.The solubility of porphyrin and its derivatives would increase after one hydrophlic group for example carboxylic group were introduced.In this paper,mono amino tetraphenylporphyrin was modified by succinic anhydride so that one carboxylic group was introduced into the target porphyrin molecule.The product was characterized by 1H NMR,IR,and UVVIS which was first published.The result of element analysis was in the line with calculation.Moreover,the solubility of 4-oxo-4-((4-(10,15,20-triphenyl 21H,23H-porphin-5-yl) phenyl) amino) botanic acid was reported.

    参考文献
    相似文献
    引证文献
引用本文

殷耀兵,陈希军,高会东.琥珀酸酐修饰的单氨基四苯基卟啉的合成与表征[J].河北工程大学自然版,2010,27(2):101-103

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2010-04-02
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2015-01-12
  • 出版日期:
文章二维码