改性高岭土吸附城市生活污水中铅的实验研究
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国家自然科学基金项目(4107203);河北省自然科学基金项目(D2009000833)


Study on lead in municipal wastewater adsorpted by surface modification of kaoline
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    摘要:

    测试了高岭土去除城市生活污水中铅离子的能力。高岭土用硫酸溶液处理,再用有机硅烷偶联剂KH580和NaOH进行表面改性。X-射线荧光分析结果显示处理过的样品SiO2/Al2O3比值为2.6:1,而未处理高岭石两者之比为1.5:1。改性高岭土吸附试验符合Shawabkeh-Tutunji等温吸附模型。在本试验中,改性高岭石表面化学吸附的最大吸附容量为54.35 mg/g。

    Abstract:

    The kaolinite clay was tested for removal of lead ions from aqueous solution. The samples were washed with sulfuric acid solution followed by chemical surface modification using KH580 and sodium hydroxide. X-ray fluoresence(XRF) results showed that the ratio of SiOZ/A1Z03 was 2.8:1for the treated sample compared to 1 .6:1 for the raw one. Different adsorption isotherm models were applied to the experimental data and found that Shawabkeh-Tutunji equation best fit these data adequately. It was also found that chemisorption took place at the surface of the modified kaolinite with maximum adsorption capacity of 54. 35 mg /g.

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张磊磊,马发韶,张宁,程伟,丁述理.改性高岭土吸附城市生活污水中铅的实验研究[J].河北工程大学自然版,2012,29(1):55-57

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  • 收稿日期:2011-10-15
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  • 在线发布日期: 2015-01-12
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