民用煤模拟燃烧排放细颗粒物的单颗粒特征及气态污染物分析
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X513

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国家自然科学基金资助项目(41807305);河北省杰出青年科学基金资助项目(D2018402149);河北省教育厅百名优秀创新人才支持计划项目(SLRC2019021);河北省人力资源和社会保障厅"三三三人才工程"人才培养项目(A201803004);河北省重点研发计划项目(19273705D)


Characterization of Single Particles and Gaseous Pollutants of Fine Particles Emitted from Simulated Residential Coal
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    摘要:

    为了解民用燃煤排放的细颗粒物的单颗粒排放特征及气态污染物排放特征,选取烟煤、无烟煤和蜂窝煤三种煤型,在实验室内进行了民用煤燃烧模拟实验及污染物排放水平监测,并采集了燃烧不同煤种细颗粒物的单颗粒样品,对其进行了气态污染水平、单颗粒微观特征及元素组成等研究。结果表明:(1)烟煤引燃阶段以链状烟尘颗粒为主,燃尽阶段以不规则形貌的矿物颗粒为主,无烟煤和蜂窝煤整个过程都以近球形粒子的有机颗粒为主。三种煤型排放颗粒物皆以碳质颗粒为主。(2)燃煤颗粒的粒径分布在0.05~0.80 μm之间,烟煤排放的烟尘集合体粒径均值在0.45~0.55 μm之间,球形粒子与蜂窝煤的球形粒子大小相近,粒径均值在0.15~0.20 μm之间,无烟煤的球形粒子相对较大,粒径均值在0.25~0.35 μm之间。(3)三种煤型的CO排放因子皆比SO2排放因子高,且烟煤的CO排放因子整体高于无烟煤和蜂窝煤。

    Abstract:

    In the effort to understand the individual particle emission characteristics and gaseous pollutants emission characteristics of fine particles emitted from residential coal combustion, three coal types, bituminous coal, anthracite and honeycomb coal, were selected to carry out combustion simulation experiment and pollutant emission level monitoring of residential coal in the laboratory, and collected the single particle samples of burning different coal fine particles, and studied the gaseous pollutants level, single particle micro characterization and element composition. The experimental results showed that:(1) In the ignition stage, the bituminous coal is mainly chain smoke particles, and in the burnout stage, it is mainly irregular mineral particles. The whole process of anthracite and honeycomb coal is dominated by near spherical particles of organic particles. Carbon particles are the main emission particles of the three coal types. (2) The particle size distribution of coal-fired can range from 0.05 μm to 0.80 μm, and the average particle size of soot aggregate emitted from bituminous coal can range from 0.45 μm to 0.55 μm. The spherical particle size of honeycomb coal is similar to that of honeycomb coal, and the average particle size of anthracite can range from 0.15 μm to 0.20 μm. The spherical particle of anthracite is relatively large, and the average particle size is between 0.25 μm and 0.35 μm. (3) The CO emission factors of three coal types are higher than SO2 emission factors, and the CO emission factors of bituminous coal are higher than that of anthracite and honeycomb coal.

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李淑娇,任秀龙,赵金波,牛红亚.民用煤模拟燃烧排放细颗粒物的单颗粒特征及气态污染物分析[J].河北工程大学自然版,2021,38(1):85-91

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  • 收稿日期:2020-10-04
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  • 在线发布日期: 2021-05-08
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