A series of nature rubber (NR) composites with modified kaolinite was prepared by melt bending. The effect of kaolin content on the flame retardancy and thermal stability of NR composites was investigated. The flame retardancy and thermal stability are obviously improved compared with the pure NR. The thermal stability of MK/NR is equivalent to CB/NR and better than PS/NR, and the flame retardancy of MK/NR equivalent to PS/NR and inferior to CB/NR when NR is filled with 50 fraction MK, PS and CB respectively. In the nature rubber matrix when it is filled by kaolin of 70 phr, the mature house-of-cards structure is edmanifest.