University personnel training is vital for the supply-side structural adjustment of industrial structure in Hebei province. Based on the construction of employment elasticity coefficient and the chain coefficient of the college graduates, this paper takes fundamental analyses of personnel training, industrial demand and deviation of both in Hebei Province. The results show that the demand for graduate talents of seven industries exceeds the supply, the graduate talents of three major departments is in excess of demand, and supply and demand of the healthy department and the agricultural sector reach a rough balance. And the path selection of the professional structure optimization of Hebei province is also put forward.