It is helpful to introduce peer education to academic counseling work, guiding students to give full play to their initiative. This study takes the City College of Dalian University of Technology as an example, focusing on how and whom to cultivate and develop as the main content. It proves that students change from passive learning to active learning process through peer education. Based on the work of City College of Dalian University of Technology as an example, it explores the significance and practice mode of academic counseling of college students from the perspective of peer education.